Reaction volume in aqueous solutions in problem solving

Marek Kosmulski

Abstract


The volumes of reactions in solution are usually ignored in problem solving. Neglection of reaction volumes may lead to errors on the order of 1 % in the final result. Calculation of the volume of neutralization reaction based on the specific densities of solutions from chemical tables is demonstrated.

Keywords


problem solving; physical chemistry; acid-base reactions; thermos-dynamics; chemical tables

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References


T. Asano, J. Lenoble, Activation and reaction volumes in solution. Chem.Rev. 78, 407-489, (1978) .

R. Van Eldik, T. Asano, W. J.Lenoble, Activation and reaction volumes in solution 2, Chem.Rev. 89, 549-688, (1978).

A. Drljaca, C.D. Hubbard, R. van Eldik, T. Asano, M.V. Basilevsky, W. J. le Noble, Activation and reaction volumes in solution. 3., Chem.Rev. 98, 2167-2289, (1978).

F. R. Longo, General Chemistry; McGraw Hill, New York, 1974, example 13.13, p. 407.

W. H. Nebergall, F. C. Schmidt, H. F. Holtzclaw, General Chemistry, D.C.Heath, Boston, 1963, example 3, p. 194.

Handbook of Chemistry and Physics, 87th ed.; CRC, Boca Ration, 2006-2007, pp.8.61 to 8.67.

Handbook of Chemistry and Physics, 87th ed.; CRC, Boca Ration, 2006-2007, p.8-79.

M. Kosmulski, E. Mączka, Dilatometric study of the adsorption of heavy-metal cations on goethite. Langmuir 20, 2320-2323, (2004).




DOI: http://dx.doi.org/10.17951/aa.2015.70.1.55
Date of publication: 2016-02-10 12:17:39
Date of submission: 2016-02-10 11:16:32


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